Food-Energy-Water Nexus in compliance with Sustainable Development Goals for integrating and managing the core environmental verticals for sustainable energy and circular economy.

Food, energy, and water resources are intricately interconnected, and nexus provides a holistic approach for addressing these complex links to minimize inefficiencies and waste. Nexus approach and circular economy are considered as effective solutions for sustainability. Quantification of these relations is the first step towards incorporating nexus modeling which helps sustainable production and consumption. For achieving the Sustainable Development Goals, understanding and effectively managing the FEW nexus becomes imperative. With an integral performance perspective, there is a need to address the interdependencies and trade-offs among food, energy, and water systems and challenges of economic, social and environmental sustainability. The aim of this study is to provide a comprehensive analysis of the FEW nexus, identify key opportunities and challenges, and propose integrated strategies for managing these core environmental verticals sustainably. The study addresses the accomplishment of these goals through nexus approaches and outlines the need for technological advancements for shared benefits among resources, contributing to conceptual development of nexus and circular economy. The results highlight the critical importance of adopting a nexus approach to advance sustainable development goals, enhance resource efficiency, and promote synergistic solutions across food, energy, and water systems.

Microalgae to biodiesel: A novel green conversion method for high-quality lipids recovery and in-situ transesterification to fatty acid methyl esters.

Greenhouse gases (GHGs) emissions due to increasing energy demand have raised the need to identify effective solutions to produce clean and renewable energy. Biotechnologies are an effective platform to attain green transition objectives, especially when synergically integrated to promote health and environmental protection. In this context, microalgae-based biotechnologies are considered among the most effective tools for treating gaseous effluents and simultaneously capturing carbon sources for further biomass valorisation. The production of biodiesel is regarded as a promising avenue for harnessing value from residual algal biomass. Nonetheless, the existing techniques for extracting lipids still face certain limitations, primarily centred around the cost-effectiveness of the process.This study is dedicated to developing and optimising an innovative and cost-efficient technique for extracting lipids from algal biomass produced during gaseous emissions treatment based on algal-bacterial biotechnology. This integrated treatment technology combines a bio-scrubber for degrading gaseous contaminants and a photobioreactor for capturing the produced CO2 within valuable algal biomass. The cultivated biomass is then processed with the process newly designed to extract lipids simultaneously transesterificated in fatty acid methyl esters (FAME) via In Situ Transesterification (IST) with a Kumagawa-type extractor. The results of this study demonstrated the potential application of the optimised method to overcome the gap to green transition. Energy production was obtained from residuals produced during the necessary treatment of gaseous emissions. Using hexane-methanol (v/v = 19:1) mixture in the presence KOH in Kumagawa extractor lipids were extracted with extraction yield higher than 12% and converted in fatty acid methyl esters. The process showed the enhanced extraction of lipids converted in bio-sourced fuels with circular economy approach, broadening the applicability of biotechnologies as sustainable tools for energy source diversification.

Comprehensive investigation of recycled PVC powder.

This study constitutes a comprehensive investigation centred on comprehending the behaviour and characteristics of recycled polyvinyl chloride (PVC) powders. The overarching objective is to successfully conclude the initial research phase, during which PVC-coated fabric offcuts undergo a transformation into PVC powder while achieving complete separation from polyethylene terephthalate fibres. The study entails a qualitative description of the morphology of PVC powder particles, employing an optical microscope to distinguish the diverse shapes exhibited by these particles. The optical microscope observations of PVC powder reveal a distinct array of non-spherical particles characterized by flat, elongated shapes. These high-magnification images unveil the intricate morphological features of the particles, highlighting their irregular shapes. Subsequently, a quantitative analysis of PVC particle size distribution is performed, comparing results from optical microscopy with those obtained through mechanical sieving. The qualitative and quantitative findings obtained provide robust evidence supporting the correlation and confirm that most particles are smaller than 600 µm (93.6%) using an optical microscope and the sieving process (96.39%). The greatest fraction (83.44%) is in the size range between 200 and 600 µm. Assessing flowability, another significant aspect in the evaluation of powders, provides insights into its behaviour and interparticle interactions. The flowability results indicate a Compressibility Index of approximately 26.84%, which suggests poor flowability. This means that the powder is likely to encounter difficulties in flowing freely. This finding is in line with the Hausner ratio, which measures 1.37. This investigation of recycled PVC powder will offer insights into the potential applications and processing considerations of this powder. More concretely, the use of recycled PVC powder shows promise as a viable alternative to conventional PVC resin in plastisol formulations, offering the potential to maintain the properties of the final PVC product without adverse effects.

The concept of food waste and food loss prevention and measuring tools.

Food waste (FW) has become a global concern, with an estimated 1.3 billion tonnes lost annually, costing about $1 trillion. Environmental and social consequences of FW are significant, contributing to 6% of European Unions' greenhouse gasemissions and affecting global food security. FW occurs is a complex issue occurring at various stages of the food supply chain (FSC) and is influenced by multiple factors such as infrastructure, available knowledge and socio-economic conditions. Developed countries FW is more prevalent at the consumption stage, whereas in the developing countries losses occur in agricultural production, post-harvest and distribution stage. Accurate quantification of FW across the supply chain is crucial and monitoring key performance indicators helps identify areas for improvement. The European Union mandates FW measurement, aligning with sustainable development goals, emphasizing the need for effective waste prevention measures. The Preferred Reporting Items for Systematic Reviews and Meta-Analyses approach was utilized to conduct a systematic literature review on FW key performance indicators (KPIs) and monitoring tools. The research identified 22 KPIs, categorized into three levels of the FSC: primary, secondary and tertiary. The most common KPIs included FW per capita, FW per portion and FW percentage. The study further discusses FW prevention measures and essential monitoring tools for addressing FW throughout the supply chain.

Mobilisation of textile waste to recover high added value products and energy for the transition to circular economy.

The textile industry is a major contributor to global waste, with millions of tons of textiles being discarded annually. Material and energy recovery within circular economy offer sustainable solutions to this problem by extending the life cycle of textiles through repurposing, recycling, and upcycling. These initiatives not only reduce waste but also contribute to the reduction of the demand for virgin materials (i.e. cotton, wool), ultimately benefiting the environment and society. The circular economy approach, which aims to recreate environmental, economic, and societal value, is based on three key principles: waste reduction, material circulation, and ecological restoration. Given these difficulties, circularity incorporates the material recovery approach, which is focused on the conversion of waste into secondary raw resources. The goal of this notion is to extract more value from resources by prolonging final disposal as long as feasible. When a textile has outlived its functional life, material recovery is critical for returning the included materials or energy into the manufacturing cycle. The aim of this paper is to examine the material and energy recovery options of main raw materials used in the fashion industry while highlighting the need of close observation of the relation between circularity and material recovery, including the investigation of barriers to the transition towards a truly circular fashion industry. The final results refer to the main barriers of circular economy transition within the industry and a framework is proposed. These insights are useful for academia, engineers, policy makers and other key stakeholders for the clear understanding of the industry from within and highlight beyond circular economy targets, SDGs interactions with energy and material recovery of textile waste (SDG 7, SDG 11, SDG 12 etc.).

Compost-assisted revegetation of highly phytotoxic sulfidic tailings with Medicago sativa L. plants grown from the seed to seedpod stage under greenhouse experimental mesocosms conditions.

The revegetation of highly phytotoxic sulfidic tailings is a challenging task which may often be successfully accomplished only following the addition of soil amendments. This study evaluated the use of green compost at increasing rates (10, 25 and 50% v/v) for the revegetation of extremely acidic sulfidic tailings of the North Mathiatis mine, Cyprus, with the use of alfalfa (Medicago sativa L.) plants, under greenhouse conditions. Alfalfa seeds were successfully germinated in tailings amended either with 25% or 50% (v/v) compost (52 and 85%, respectively). Plants managed to complete their life cycle and produce seeds only in the tailings amended with 50% (v/v) compost, since plants grown in tailings amended with lower rates of compost (i.e., 10 or 25% v/v) showed severe symptoms of phytotoxicity and eventually died. The amendment of tailings with 50% (v/v) green compost resulted in increased pH values, water holding capacity and organic content levels, soil respiration rates, as well as changes in soil elemental composition compared with tailings alone treatment, which in turn facilitated the growth and development of alfalfa plants during the whole experimental period (140 days). Plants managed to reach the late seedpod growth stage, indicating their potential regeneration and continual existence to the amended tailings, simultaneously uncovering the development of favorable conditions in the rhizosphere for the successful revegetation of studied tailings.

Waste metrics in the framework of circular economy.

There are several sustainability issues that the linear economy of today's society cannot adequately tackle (i.e. resource depletion, waste treatment, etc.). As a result, the scientific community and policymakers give high priority to the implementation of the circular economy concept. The sustainable development goals of the United Nations are in line with the European Union's (EU) commitment to a smooth transition to a circular economy. Circular business models require a shift in technical elements involving R strategies to replace traditional business models (i.e. reuse, reduce, recycle, etc.). Monitoring circular economy to provide quantifiable, measurable data is necessary for a successful transition. Monitoring tools (i.e. Key Performance Indicators, quality protocols) enable decision-makers to measure circular economy performance and identify circularity's advantages and disadvantages. To stimulate the adoption of a circularity model addressing critical issues of excessive waste production and resource use, this mini review aims to address the literature gap of waste metrics in the framework of circular economy and offer insights on circular economy indicators to aid for a seamless transition to a more sustainable society. For this purpose, Preferred Reporting Items for Systematic Reviews and Meta-Analysis method was chosen to assess literature. The authors collected and analysed data from 101 records, 70 articles and 31 reports related to the topic under consideration. Through the literature review, it is obvious that moving away from linear production model frequently leads to the development of new internal capabilities along the value chain and, eventually, high efficiency that reduces costs, increasing productivity, encourages brand names, minimizes threats, creates new products and fulfils regulations and green consumer expectations.

LCA of municipal wastewater treatment.

Wastewater treatment plants play a significant role in minimizing environmental pollution by treating wastewater and reducing the release of contaminants into the environment. However, their operation can still have an environmental footprint. Therefore, Life Cycle Assessment (LCA) of wastewater treatment provides a comprehensive framework to quantify the environmental impact of plants across various categories. By conducting LCA assessments, the environmental impacts of different scenarios or treatment technologies can be compared, enabling decision-makers to identify the most environmentally friendly options. This information helps in optimizing the plant's design, operation, and resource allocation to minimize their environmental burden. The current research hypothesis was to conduct an LCA of a typical activated sludge plant in Greece, considering three different scenarios in order to provide an innovative take on wastewater treatment plant foam waste and utilize them for the production of biogas through anaerobic digestion. The assessment was carried out using OpenLCA software as well as EcoInvent v3.3. database. The study focused on the impact assessment of five categories (eutrophication potential, acidification potential, global warming potential, ozone depletion, and photochemical ozone creation). The results indicated that the baseline scenario had the highest impact on these categories, followed by Scenario I, while Scenario II had the least impact. Additionally, the cumulative energy demand assessment showed that the baseline scenario required significantly more energy compared to Scenarios I and II. However, Scenario II, which involved fine screens and utilization of biogas, exhibited the highest energy production, thereby reducing the overall energy demands for the system. Based on these findings, it is crucial for wastewater treatment facilities to actively pursue energy demand mitigation strategies by implementing energy-efficient technologies and utilizing biogas. These measures not only contribute to environmental protection but also promote a greener and more sustainable future for WWTP operations.

Construction and demolition waste framework of circular economy: A mini review.

As the demand for materials continues to increase and building lifespans shorten, the construction industry faces mounting pressure to reduce its material and environmental impacts. Mismanagement of construction and demolition waste (CDW) can have severe environmental consequences. To address this, material recovery and circular economy approaches offer significant potential for reducing construction waste through the sustainable use of resources. Existing circular economy and material recovery models that prioritize recycling and reuse efforts demonstrate a sustained commitment to supporting circular practices in the construction and demolition sector. The goal is to minimize waste production, which poses environmental challenges such as raw material shortages and sustainability concerns. Using Preferred Reporting Items for Systematic Reviews and Meta-Analyses statement for recruiting relevant literature, this mini review aims to identify the obstacles to implementing circular economy practices in the construction industry, while exploring opportunities for material recovery and circularity. The ultimate aim is to facilitate a fair and smooth transition towards sustainable development, while addressing environmental, social and economic barriers. A more sustainable and circular approach to building construction and management can be attained by considering all the aspects of the CDW cycle, resulting in significant benefits for the environment and society as a whole.

Urbanization and solid waste production: prospects and challenges.

The increasing urban population and the restructuring of urban economies are the main aspects that determine urban development in the twenty-first century. Rapid urbanization is among the most significant anthropogenic factors that impact ecosystems and sustainability. Urbanization is a "double-edged sword." Even though it contributes to economic prosperity and social development, at the same time, it poses severe challenges to the natural environment and social system. The scientific community emphasizes the need to investigate the relationship between cities and the environment to comprehend their dynamic interactions related with problems such as climate change, consumption of natural resources, and life quality degradation. Population growth and urbanization are central considerations of the 2030 Agenda of the United Nations Sustainable Development Goals, particularly SDG 11, dealing with making cities inclusive, safe, resilient, and sustainable. Moreover, the new circular economy model is receiving increasing attention globally as a solution to the current production and consumption model, which is based on constant growth and increasing resource input. The objective of this paper was to identify the major challenges occurred due to the rapid urbanization in a coastal city though a qualitative and quantitative waste compositional analysis. The ultimate goal is to propose the waste compositional analysis as a new indicator in the literature for determination of the degree of metabolism in an island region. According to the compositional analysis, the higher the population density in a region, the greater the volume of garbage produced and, consequently, the infrastructure necessary for waste management. Also, the increased seasonal tourist activity leads to an increase in the number of tourist accommodations and services. The results provided may also be applicable in other cities with similar characteristics related with tourism habits and the challenges they may face as a result of the waste production.

N-Source Determines Barley Productivity, Nutrient Accumulation, and Grain Quality in Cyprus Rainfed Agricultural Systems.

The Eastern Mediterranean and Middle East (EMME) region is already experiencing the negative effects of increased temperatures and the increase in prolonged drought periods. The use of organic fertilization could be a valuable tool to meet the main challenges of climate change and maintain the productivity, quality, and sustainability of rainfed agricultural ecosystems. In the current study, we compare the effect of manure, compost, and chemical fertilization (NH4NO3) on barley grain and straw yield in a field study for three consecutive growing seasons. The hypothesis that the barley productivity, nutrient accumulation, and grain quality remain similar among the different nutrient management strategies was tested. The results showed that both growing season and type of nutrient source significantly affected barley grain and straw yield (F6,96 = 13.57, p < 0.01). The lowest productivity was noticed in the non-fertilized plots while chemical and organic fertilization exhibited similar grain yield, ranging from 2 to 3.4 t/ha throughout the growing seasons. For straw, the use of compost had no effect on the yield in any of the growing seasons examined. The use of manure and compost had a significant effect on grain macro- and micronutrient content but this was highly related to growing season. Principal component analysis (PCA) clearly demonstrated the discrimination of the different type of fertilization on barley performance during the course of the study, while the application of compost was highly associated with an increase in micronutrients in grain samples. Furthermore, structural equational modeling (SEM) showed that both chemical and organic fertilization had a direct positive effect on macro- (r = 0.44, p < 0.01) and micronutrient (r = 0.88, p < 0.01) content of barley grain and a positive indirect effect on barley productivity through N accumulation in grain (ß = 0.15, p = 0.007). The current study showed that barley grain and straw yield was similar between manure and NH4NO3 treatments, while compost exhibited a residual positive effect causing an increase in grain yield during the growing season. The results highlight that N fertilization under rainfed conditions is beneficial to barley productivity through its indirect effects on N accumulation in grain and straw, while it improves grain quality through the increased accumulation of micronutrients.

Nitrogen management in farming systems under the use of agricultural wastes and circular economy.

Population growth leads to an increase in the demand for energy, water, and food as cities grow and urbanize. However, the Earth's limited resources are unable to meet these rising demands. Modern farming practices increase productivity, but waste resources and consume too much energy. Agricultural activities occupy 50 % of all habitable land. After a rise of 80 % in 2021, fertilizer prices have increased by nearly 30 % in 2022, representing a significant cost for farmers. Sustainable and organic farming has the potential to reduce the use of inorganic fertilizers and increase the utilization of organic residues as a nitrogen (N) source for plant nutrition. Agricultural management typically prioritizes nutrient cycling and supply for crop growth, whereas the mineralization of added biomass regulates crop nutrient supply and CO2 emissions. To reduce overconsumption of natural resources and environmental damage, the current economic model of "take-make-use-dispose" must be replaced by "prevention-reuse-remake-recycle". The circular economy model is promising for preserving natural resources and providing sustainable, restorative, and regenerative farming. Technosols and organic wastes can improve food security, ecosystem services, the availability of arable land, and human health. This study intends to investigate the nitrogen nutrition provided by organic wastes to agricultural systems, reviewing the current state of knowledge and demonstrating how common organic wastes can be utilized to promote sustainable farming management. Nine waste residues were selected to promote sustainability in farming based on circular economy and zero waste criteria. Using standard methods, their water content, organic matter, total organic carbon, Kjeldahl nitrogen, and ammonium levels were determined, along with their potential to improve soil fertility via N supply and technosol formulation. 10 % to 15 % of organic waste was mineralized and analysed during a six-month cultivation cycle. Through the results, the combination of organic and inorganic fertilization to increase crop yield is recommended, as is the search for realistic and practical methods of dealing with massive amounts of organic residues within the context of a circular economy.

Tomato waste biochar in the framework of circular economy.

Tomato pomace was slowly pyrolyzed at 350 and 550 °C (under an N2 flow of 50 L/h) at a rate of 6 °C/min and a residence time of 1:30 h to produce two biochars named B350 and B550, respectively. In addition, the two biochars were chemically activated with ΚΟΗ (at a ratio of 1:10 w/v) at 800 °C to produce two new materials named BA350 and BA550. The four biochars produced were characterized physically and chemically (pH, yield, calorific value). They were also analyzed by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (B.E.T), elemental analysis (EA), and thermogravimetric analysis (TGA). The results showed that as the pyrolysis temperature increased (350 to 550 °C), the specific surface area (SSA) increased. The latter was also significantly increased by the activation process. EA showed a variation in the mineral content of the produced biochars, resulting in a different content of the biochars after activation. The parameters studied showed that biochars from tomato waste could be used as an organic amendment to improve soil fertility in agricultural. In addition, because of their ability to absorb water, they could be used as a water reservoir in soils in arid areas.

LCA of Barley Production: A Case Study from Cyprus.

Greenhouse gas emissions (i.e., carbon dioxide, methane, nitrous oxide) produced by agriculture contribute to global warming and climate change. Various practices followed by farmers in different environmental conditions contribute to the increase in the phenomena, and there is a need for immediate measures. The current study examines the environmental impact of barley production under rain-fed conditions in Cyprus. For this, four different nutrient management scenarios were investigated in order to evaluate the environmental performance of crop production, namely: (1) Nitrogen (20%), Phosphorous (20%), Potassium (10%); (2) Nitrogen (20%), Phosphorous (20%), Potassium (10%) and manure; (3) Nitrogen (25%), Phosphorous (10%), Potassium (0%); and (4) Nitrogen (25%), Phosphorous (10%), Potassium (0%) and manure. Data were collected from two different areas of Cyprus (Nicosia and Larnaca) through on-site visits and questionnaires. Life Cycle Assessment (LCA) was used as a method to quantify environmental impacts which were categorized into six impact categories: (i) acidification potential (AP), (ii) eutrophication potential (EP), (iii) global warming potential (GWP), (iv) ozone depletion potential (ODP), (v) photochemical, ozone creation potential (POCP), and (vi) terrestrial ecotoxicity (TAETP). LCA was used with system boundaries from field to harvest and a functional unit (FU) of one bale of hay. Research results showed that the addition of manure increased values in all impact categories. Comparing scenarios without manure (1 and 3) and with manure (2 and 4), the main process which contributed to GWP was field preparation, which resulted in 3 t CO2-Eq∙FU-1 and 46.96 t CO2-Eq∙FU-1, respectively. Furthermore, the highest contribution of sub-processes to GWP (kg CO2-Eq∙FU-1) was machinery maintenance (scenarios 2 and 4). The potential to reduce environmental impacts from barley and moreover, to mitigate the footprint of the agriculture sector in Cyprus is proposed by changing existing practices such as decreasing fuel consumption by agricultural machinery, and monitoring fertilizing and seeding. Conclusively, the carbon footprint of barley can be decreased through the improvement of nutrient management and cropping practices.

The perception of circular economy in the framework of fashion industry.

Humanity's three main components are energy, food and clothing. Each of us, individually and collectively, contributes to climate change and CO2 emissions, natural resource consumption, and social attitudes and behaviour. Global fashion trends are expected to increase in value from 1.5 trillion dollars in 2020 to around 2.25 trillion dollars by 2025, indicating that the fashion demand is on the rise. Due to climate change, soil and water scarcity, and a variety of other diseases, new natural resources must be developed from plastic fibres, natural colours must replace synthetic ones, water consumption must be reduced and the 'buy-and-throw-away philosophy' must be replaced with 'buy-less-and-these-are-needed' and incorporate the 12 'R' strategies to aid the transition to a circular economy. In the context of waste management as well as on the development of new strategy approach, the fashion industry requires a new business circular model and furthermore a new mindset.

Iodide Removal by Resorcinol-Formaldehyde Carbon Aerogels.

The adsorption technique is widely used in water purification, and its efficiency can be significantly improved by target-specific adsorbent design. Research on iodine and its ion removal from water has attracted a great deal of interest due to increased concentrations in the environment and acute toxic effects, e.g., in human thyroid cells. In this work, the iodide removal performance of two high-surface-area resorcinol-formaldehyde-based carbon aerogels was studied under acidic conditions. The BET surface area was 790 m2/g (RF_ac) and 375 m2/g (RMF-GO), with a corresponding micropore ratio of 36 and 26%, respectively. Both aerogels showed outstanding adsorption capacity, exceeding the reported performance of other carbons and Ag-doped materials. Owing to its basic nature, the RMF-GO carbon aerogel showed higher I- capacity, up to 97 mg/g, than the acidic RF_ac, which reached a capacity of 82 mg/g. The surface chemistry of the aerogels also played a distinct role in the removal. In terms of kinetics, RF_ac removed 60% of the iodide ions and RMF-GO 30% within 8 h. The removal kinetics was of the first order, with a half-life of 1.94 and 1.70 h, respectively.

Unified waste metrics: A gamified tool in next-generation strategic planning.

A gamification approach for tackling waste management planning and urban development provide a more engaging and interactive experience with high pedagogical potential. Existing serious games involving waste management are complex in their data ingestion, use, and presentation, limiting individuals' opportunities to gain knowledge and decision-making skills transferrable to the real world. Simulations, by comparison, provide either an oversimplified and unrealistic user interface or explore in depth individual rather than aggregate key performance indicators for waste management, limiting potential knowledge retention. There is a clear opportunity in creating an informative, easy-to-use simulation-based game to help stakeholders build understanding of waste management policies, performance, and causal relationships. This gamified tool provides clear feedback through quick-visibility performance indicators (i.e., waste accumulation index, waste compositional analysis, prevention activities etc.) and offers the opportunity, through multi-criteria decision making, of simulating real-life scenarios and previewing the possible outcomes of certain in-game actions. The research question is how the process of gamification might serve as powerful tool for educating decision makers. The results are considered as a reference point to any policy maker intending to assess environmental performance, proposed activities to reach Circular Economy targets, and European Green Deal and UN Sustainable Development Goals.